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  1. Abstract

    The small sample size of tropical cyclone (TC) genesis in the observations prevents us from fully characterizing its spatiotemporal variations. Here we take advantage of a large ensemble of 60-km-resolution atmospheric simulations to address this issue over the northwest Pacific (NWP) during 1951–2010. The variations in annual TC genesis density are explored separately on interannual and decadal time scales. The interannual variability is dominated by two leading modes. One is characterized by a dipole pattern, and its temporal evolution is closely linked to the developing ENSO. The other mode features high loadings in the central part of the basin, with out-of-phase changes near the equator and date line, and tends to occur during ENSO decay years. On decadal time scales, TC genesis density variability is primarily controlled by one mode, which exhibits an east–west dipole pattern with strong signals confined to south of 20°N and is tied to the interdecadal Pacific oscillation–like sea surface temperature anomalies. Further, we investigate the seasonal evolution of the ENSO effect on TC genesis density. The results highlight the distinct impacts of the two types of ENSO (i.e., eastern Pacific vs central Pacific) on TC genesis density in the NWP during a specific season and show the strong seasonal dependency of the TC genesis response to ENSO. Although the results from the observations are not as prominent as those from the simulations because of the small sample size, the high consistency between them demonstrates the fidelity of the model in reproducing TC statistics and variability in the observations.

     
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  2. Abstract

    Most El Niño events decay after a peak in boreal winter, but some persist and strengthen again in the following year. Several mechanisms for regulating its decay pace have been proposed; however, their relative contributions have not been thoroughly examined yet. By analyzing the fast-decaying and persistent types of the events in a 1200-yr coupled simulation, we quantify the key dynamic and thermodynamic processes in the decaying spring that are critical to determining the decay pace of El Niño. The zonal advection due to upwelling Kelvin wave accounts for twice as much the cooling difference as evaporation or meridional advection does. The upwelling Kelvin wave is much stronger in the fast-decaying events than the others, and its strength is equally attributed to the reflected equatorial Rossby wave and the equatorial easterly wind forcing over the western Pacific in the preceding 2–3 months. Relative to the fast-decaying events, the evaporative cooling is weaker but the meridional warm advection is stronger in the persistent events. The former is due to more meridionally asymmetric wind and sea surface temperature anomalies (SSTA) signaling positive Pacific meridional mode. The latter results from the advection of equatorial warm SSTA by climatological divergent flow, and the warmer SSTA persists from the mature stage subject to weaker cloud-radiative cooling in response to the central-Pacific-type SSTA distribution in the persistent events relative to the fast-decaying events. Our result consolidates the existing knowledge and provides a more comprehensive and physical pathway for the causality of El Niño’s diverse duration.

     
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  3. Abstract

    The cycle life of rechargeable lithium (Li)‐metal batteries is mainly restrained by dendrites growth on the Li‐metal anode and fast depletion of the electrolyte. Here, we report on a stable Li‐metal anode enabled by interconnected two‐dimensional (2D) arrays of niobium nitride (NbN) nanocrystals as the Li host, which exhibits a high Coulombic efficiency (>99 %) after 500 cycles. Combining theoretical and experimental analysis, it is inferred that this performance is due to the intrinsic properties of interconnected 2D arrays of NbN nanocrystals, such as thermodynamic stability against Li‐metal, high Li affinity, fast Li+migration, and Li+transport through the porous 2D nanosheets. Coupled with a lithium nickel–manganese–cobalt oxide cathode, full Li‐metal batteries were built, which showed high cycling stability under practical conditions – high areal cathode loading ≥4 mAh cm−2, low negative/positive (N/P) capacity ratio of 3, and lean electrolyte weight to cathode capacity ratio of 3 g Ah−1. Our results indicate that transition metal nitrides with a rationally designed structure may alleviate the challenges of developing dendrite‐free Li‐metal anodes.

     
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